No. Only drivers named on your booking can drive the car. Anyone else isn't insured, so you pay the full cost of any damage, and it breaks your hire agreement.
Want someone else to drive?
Add them as an additional driver before they drive. They need to pass the same licence and ID checks. See can I let someone else drive the vehicle.
You stay responsible
The main driver is responsible for the car for the whole hire, including fines. See who is responsible for the vehicle during the hire.